⌘+K

Pulse Explore Communities Researchers Journals

Home Communities Explore

January 1, 1988Journal of the Chemical Society Chemical Communications

The first rhenium oxo–alkylidene complex. X-Ray structure of ReO ₂ [C(H)CMe ₃ ](CH ₂ CMe ₃ )

Shiang Cai David M. Hoffman Derk A. Wierda

View at Publisher

Ask AI

Bookmark

Share

Ask about this paper

Answers are grounded in this paper and cite their sources.

Ask your own question…

Abstract

Photolysis of ReO2(CH2CMe3)3 in pyridine gives the alkylidene complex ReO2[C(H)CMe3](CH2CMe3) in 76% yield; an X-ray crystallographic study shows ReO2[C(H)CMe3](CH2CMe3) has a distorted tetrahedral structure.

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Cai et al. (1988) studied this question.

synapsesocial.com/papers/6a70efdbac440176ef299e74 https://doi.org/10.1039/c39880001489

View at Publisher

Ask AI

Bookmark

Share

Keep reading

Synapse has enriched 10 related papers. Consider them for comparative context:

1Synthesis and structure of Ba2InO3F: oxide/fluoride ordering in a new K2NiF4 superstructureJournal of the Chemical Society Chemical Communications · 1995
2A new MAS NMR probe for in situ investigations of hydrocarbon conversion on solid catalysts under continuous-flow conditionsJournal of the Chemical Society Chemical Communications · 1995
3Formation of methanol by the gas phase partial oxidation of methane under normal pressuresJournal of the Chemical Society Chemical Communications · 1995
4Detection of regioisomeric macrocyclic tetraethers in the lipids of Methanobacterium thermoautotrophicum and other archaeal organismsJournal of the Chemical Society Chemical Communications · 1995
5Photoinduced SET for the functionalization of alkanesJournal of the Chemical Society Chemical Communications · 1995
6Catalytic formation of aziridines from imines and diazoacetateJournal of the Chemical Society Chemical Communications · 1995
7Identification of DTX-4, a new water-soluble phosphatase inhibitor from the toxic dinoflagellate Prorocentrum limaJournal of the Chemical Society Chemical Communications · 1995
8Base and acid catalysis by the alkali-containing MCM-41 mesoporous molecular sieveJournal of the Chemical Society Chemical Communications · 1995
9Free radical scavenging activity of water-soluble fullerenolsJournal of the Chemical Society Chemical Communications · 1995
10Room-temperature formation of molecular sieve MCM-41Journal of the Chemical Society Chemical Communications · 1995

More from Journal of the Chemical Society Chemical Communications