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Adding benzoic acid and aniline as cocatalysts to the RhI/2-amino-3-picoline catalyzed hydroacylation of alkenes with aldehydes to give ketones results in a remarkable improvement in yield and activity [for example, Eq. (1)]. This is one of the few examples of a successful intermolecular hydroacylation reaction.
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Jun et al. (2000) studied this question.
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