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January 1, 1980Journal of the Chemical Society Chemical Communications

Protonated dimethyl sulphoxide, [Me2SO ? H ? OSMe2]+; a novel hydrogen-bridged structure: X-ray crystal structure of trans-[H(Me2SO)2][RhCl4(Me2SO)2]

Brian R. James Robert H. Morris Frederick W. B. Einsten Anthony C. Willis

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Abstract

Studies on salts of tetrachlororhodate(III) containing sulphoxide ligands show the existence of the hydrogen-bonded cation [Me2SO ⋯ H ⋯ OSMe2]+ with a very short O ⋯ H ⋯ O bond length of 2·42 Å.

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Cite This Study

James et al. (1980) studied this question.

synapsesocial.com/papers/6a71caae660549caf2c646b1 https://doi.org/10.1039/c39800000031

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