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Relative intensities and appearance potentials of several positive ions in the mass spectrum of PF 3 are reported as well as an ionization efficiency curve for F − , the only negative ion of significant intensity. Probable ion fragmentation pathways are proposed, together with heats of formation of some positive ions, and ionization potentials for PF 3 , PF 2 ·, and PF. The results are compared with available data for other Group V halides.
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Torgerson et al. (1975) studied this question.
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