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Nitrido- and imido-osmium(VI) complexes with cyanides as ligands have been synthesised and found to display intense photoluminescence in fluid solutions at room temperature; the X-ray structure of [Ph4As]2[OsVI(CN)5N] has been determined with a measured OsN distance of 1.647(7)Å.
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Che et al. (1989) studied this question.
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