Answers are grounded in this paper and cite their sources.
The synthesis of trans-[RuVI(L)(O)2]Y2(Y = PF6 or ClO4) and trans-[RuIV(L)(NCO)(O)]ClO4{L =meso-1,2,6,10,11-pentamethyl-2,6,10-triaza[11](2,6)pyridinophane} is described; irradiation of trans-[RuVI(L)(O)2]2+ and [OsVI(CN)4(O)2]2–(λ > 330 nm) in presence of organic substrates yielded the corresponding oxidized organic products indicating that the (dxy)1(dπ*)1 excited states of RuVI- and OsVI-oxo complexes are reactive towards epoxidation of alkenes and to oxidation of C–H bonds.
No takes yet. Share an insight, caveat, or question.
Yam et al. (1988) studied this question.
Synapse has enriched 10 related papers. Consider them for comparative context: