Synthetic investigation reveals an efficient three-component coupling in alkynylbenzaldehyde systems, suggesting a facile pathway to functionalized dihydroisoquinolines.
AgOTf was discovered as a highly efficient catalyst in reactions of 2-alkynylbenzaldehydes, amines, and diethylphosphite, which provided a facile and efficient pathway for the synthesis of 2,3-disubstituted-1,2-dihydroisoquinolin-1-ylphosphonates.
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Sun et al. (2007) studied this question.
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