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January 1, 1986Journal of the Chemical Society Chemical Communications

Synthesis and reactivity of a monomeric 14-electron ‘bare’ ruthenium( II ) porphyrin complex; reversible binding of dinitrogen to form mono- and bis-dinitrogen complexes

Mark J. Camenzind Brian R. James David Dolphin

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Abstract

The 14-electron species Ru(TMP), obtained via vacuum pyrolysis of Ru(TMP)(MeCN)2, reacts with a plethora of ligands to form bis-ligated species, including the first bis(dinitrogen) metalloporphyrin complex [TMP = the dianion of 5, 10, 15,20-tetramesitylporphyrin].

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Camenzind et al. (1986) studied this question.

synapsesocial.com/papers/6a867676b81bbc5ca863a7e6 https://doi.org/10.1039/c39860001137

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