1H-Imidazo[4,5-f][1,10]phenanthroline (Hip) can be deprotonated to bridge Zn(II) ions, giving a flexible porous metal azolate framework [Zn7(ip)12](OH)2 (MAF-34) which shows not only drastic structural and luminescent changes for different solvent vapors, but also strong adsorption and quantitative luminescence response for low-pressure CO2.
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Qi et al. (2011) studied this question.
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