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A synthesis of protected C-2β- and C-2α-fluoro oleandrosyl fluorides is presented; coupling of these carbohydrates with avermectin B1a monosaccharide 5-O-t-butyldimethylsilyl derivative, followed by deprotection, furnished the title compounds whose biological activity was evaluated.
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Bliard et al. (1987) studied this question.
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