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Perspective review demonstrates versatile applications of aryl trifluoromethyl diazoalkanes in organic synthesis, highlighting their utility as donor-acceptor carbene precursors.
High Resolution Image Download MS PowerPoint Slide Aryl trifluoromethyl diazoalkanes and diazirines have become unique as reactants in synthetic methodology. As privileged compounds containing CF 3 groups and ease of synthetic access, aryl trifluoromethyl diazoalkanes and diazirines have been highlighted for their versatility in applications toward a wide range of synthetic transformations. This Perspective highlights the synthetic applications of these reactants as precursors of stabilized metal carbenes, i.e., donor–acceptor-substituted ones.
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Ollevier et al. (2022) studied this question.
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