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January 1, 1985Journal of the Chemical Society Chemical Communications

X-Ray structural analysis of a tetra-manganess( II ) complex of a new (4 × 4) Schiff-base macrocycle incorporating a cubane-like Mn 4 (alkoxy) 4 core

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Abstract

X-Ray structure analysis of the tetranuclear Schiff-base macrocylic complex [C12H14N3OMnII]4(ClO4)4 shows the (4 × 4) macrocycle is folded so that the four alkoxide oxygen atoms cap the faces of a tetrahedral Mn4 cluster, resulting in a cubane-type stereochemistry.

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Vickie McKee (1985) studied this question.

synapsesocial.com/papers/6a962791c5c42aa888d22b5b https://doi.org/10.1039/c39850000158

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