Ethylchloro-, isopropylchloro-, and t-butylchloro-carbenes have been generated by photolysis of the corresponding 3-alkyl-3-chlorodiazirines and added to several alkenes; the partition between intermolecular interception and intramolecular liquidation of the carbenes was mainly dependent on the structure of the carbenic alkyl groups.
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Moss et al. (1978) studied this question.
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