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An efficient cyanation of styrenyl bromides by K(4)[Fe(CN)(6)] has been achieved under the catalysis of hydroxyapatite-supported copper(I) producing a variety of functionalized cinnamonitriles in high yields. The stereochemistry of the styrenyl double bond is preserved during the process providing the same stereoisomer of product.
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Saha et al. (2011) studied this question.
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