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Reaction of octakis(dimethylamino) porphyrazine 1 with [60]fullerene gives a crystalline 2:1 charge-transfer (CT) complex as a three-dimensional network of chains; in contrast, reaction of 1 with tetracyanoquinodimethane (TCNQ) gives a crystalline 1:1 charge transfer salt as one-dimensional integrated stacks.
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Eichhorn et al. (1995) studied this question.
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