The X-ray crystal structure of [(FeC5Me5)2(µ2,η10-biphenyl)]+PF6–,(1)+, shows a 37-electron configuration indicating that the two-electron transfer (1)2+(36e)→(1)+(37e)→(1)(36e) proceeds with structural reorganization and stabilization in the second electron transfer.
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Astruc et al. (1990) studied this question.
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