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The formation of a 3-methylbuta-1,2-diphenylpalladium(II) complex (2) from the prop-2-ynylic chloride (1a) or the prop-2-ynylic acetate (1b) and tetrakis(triphenylphosphine)palladium(0), as well as its conversion into the allenes(4), is described.
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Elsevier et al. (1983) studied this question.
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