The electronic spectrum of [Zn4O(acetate)6] in solution is characterized by an absorption (λmax.= 216 nm) and emission (λmax.= 372 nm) band; it is assigned to a ligand-to-metal charge-transfer (LMCT) transition, which corresponds to the band-gap transition of the semiconductor ZnO.
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Kunkely et al. (1990) studied this question.
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