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September 3, 2026Materials Today CommunicationsOpen Access

Brushite(CaHPO4·2H2O) prepared by spontaneous precipitation with different phosphate salts and calcium lactate derived from scallop shell wastes

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Authors

BBBanjong BoonchomSPSirichet PunthipayanonWBWimonmat Boonmee

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Overview

Experimental study demonstrates high-yield brushite synthesis from scallop shell waste, suggesting an eco-friendly route for industrial calcium phosphate production.

Key Points

  • To investigate the spontaneous precipitation and structural characteristics of brushite synthesized from scallop shell waste-derived calcium lactate and various phosphate salts.
  • Synthesized brushite by reacting calcium lactate extracted from scallop shell waste with sodium, potassium, or ammonium phosphate salts (M2HPO4, where M = Na, K, NH4).
  • Characterized sample properties using thermal analysis, factor group splitting vibrational analysis, X-ray diffraction (XRD), and scanning electron microscopy (SEM).
  • Brushite Na achieved the highest production yield at 97.32%, whereas Brushite NH4 exhibited the highest purity at 86.28%.
  • Thermal analysis confirmed the presence of 2.5 mol H2O hydration water, while XRD and SEM verified pure monoclinic crystal structures displaying plate-like morphology with a dominant diffraction peak at ~11.65° (hkl = 020).

Cite This Study

Boonchom et al. (2026) studied this question.

synapsesocial.com/papers/6a9935d8636c6408cfa7e643https://doi.org/10.1016/j.mtcomm.2026.116050
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