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Two epimeric 3,3′-dihydroxy-ε,ε-carotenes have been identified from the skins of the yellow Costa Rican frog, Atelopus chiriquiensis; both compounds have the (6R,6′R,3′S) stereochemistry but differ in absolute configuration at C-3.
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Bingham et al. (1977) studied this question.
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