Pick one out of three: Acyclic and cyclic 1,2,3-triols are silylated with exceptional site- and enantioselectivity by a small-molecule catalyst to afford silyl ethers having a neighboring diol moiety. The new process is applied to the enantioselective total syntheses of three cleroindicins, natural products isolated from a plant used in China to battle malaria and rheumatism.
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You et al. (2008) studied this question.
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