The square‐antiprismatic structure of IF corresponds to that of XeF . This shows that the extra lone pair of XeF is located in a stereochemically inactive orbital. The counterion NO⊕(NOF)2 is a polymer in which the charge‐carrying N atom is surrounded by one O and four F atoms in a square‐pyramidal arrangement.
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Mahjoub et al. (1991) studied this question.
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