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Catalytic hydrosilylation of CO 2 is an efficient and selective approach to form chemicals. Herein, we describe the first iron catalysts able to promote the reductive functionalization of CO 2 using hydrosilanes as reductants. Iron( ii ) salts supported by phosphine donors enable the conversion of CO 2 to formamide and methylamine derivatives under mild reaction conditions.
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Frogneux et al. (2014) studied this question.
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