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The reactive ion etching in InGaAsP and InP have been characterized in methane-based plasma. The role of H2, He, and Ar as diluents have been investigated. Highly anisotropic short-period gratings with periods as small as 0.2 μm and with smooth etched surfaces are presented. Auger electron spectroscopy has been used to delineate a proper processing sequence to obtain etched surfaces as clean as the surface of control samples. The CH4/He gas mixture is suggested for the fabrication of gratings as a compromise for achieving good etched profiles as well as to minimize hydrogen passivation of donors in etched samples.
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Andideh et al. (1989) studied this question.
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