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The optimized one-pot synthesis of 16 new 2-coumaranones containing a carbamate side-chain is described.Furthermore, the quantum yields for the base-activated chemiluminescence in the presence of oxygen was determined for all compounds, with a maximum of 5.9 ± 0.1 x 10 -2 E mol -1 , and the application of these compounds as substitutes for usual bioluminescent and chemiluminescent reagents in bioassays is anticipated.A preliminary mechanistic pathway is also suggested, making use of recent developments regarding aspects of organic chemiluminescence, in agreement with both experimental and theoretical data available on the induced 1,2-dioxetanone decomposition as well as with the high efficiency of this reaction.
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Schramm et al. (2015) studied this question.
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