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The solid transition-metal chalcogenide fluorides, WF4S, WF4Se, and ReF4S have been prepared in high yield and their chemistry has been examined; X-ray crystallography has shown that WF4S and ReF4S have fluorine bridged polymeric chain structures whilst WF4S·MeCN is a monomer.
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Holloway et al. (1983) studied this question.
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