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Reaction between BiX2Ph (X = Cl or I) and 4,4'-bipy afforded crystals of complexes trans-[BiX2Ph(4,4'-bipy)]n as solvates in which an anticipated combination of dative (Bi?bipy) and secondary bonding (Bi⋯X) leads to a controlled polymeric structure.
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James et al. (2000) studied this question.
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