The tert-butyldimethylsilyl nitronate derived from 1-nitropropane was condensed with 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosylthiol to yield two geometrically isomeric thiohydroximates; the Z-isomeric form was then converted by conventional procedures into potassium ethylglucosinolate ("glucolepidiin").
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Keller et al. (1984) studied this question.
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