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Two birds with one stone: Cooperative assembly of four-connected indium nodes with two symmetry-complementary ligands leads to both three-ring-based zeolite-type metal–organic frameworks (NPO-type) and the Johnson-type metal–organic polyhedra shown in the picture (gray C, green In, blue N, red O). The NPO-zeolite compounds behave as semiconductors and exhibit photocatalytic activity for the generation of dihydrogen from water under ultraviolet irradiation.
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Zheng et al. (2011) studied this question.
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