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January 1, 1991Journal of the Chemical Society Chemical Communications

The reactions of [FeH(H2)(Me2PCH2CH2PMe2)2][BPh4] with allenes and acetylenes, and the reduction of cyclopropane by molybdenum nitrogenases

Adrian Hills David L. Hughes M. Jimenez-Tenorio G. Jeffery Leigh Cathy A. McGeary Adrian T. Rowley Marjorie D. Bravo Charles E. McKenna Marie-Claire McKenna

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Abstract

The reduction of cyclopropenes by metal hydrides shows significant parallels with their reduction by Klebsiella pneumoniae nitrogenase; intermediates isolated from the reduction of the isomeric allenes and acetylenes by [FeH(H2)(Me2PCH2CH2PMe2)2][BPh4] show novel features of much wider implication.

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Hills et al. (1991) studied this question.

synapsesocial.com/papers/6aae0a0e694abce6c84f681f https://doi.org/10.1039/c39910000522

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