Excess volumes for binary mixtures of toluene with 1-propanol, 2-propanol, 1-butanol, 2-methyl-1-propanol, 1-pentanol, 1-hexanol, 1-heptanol, and cyclohexanol have been measured as a function of composition at 303.15 K by a dilatometric method. The excess volume curves for 1-propanol and 1-butanol are sigmoid. For other alcohols VE values are positive over the entire composition range.
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Swamy et al. (1980) studied this question.
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