Experimental characterization demonstrates abrupt spin-crossover with a 45 K hysteresis loop in an iron(III) complex, highlighting potential utility in thermal molecular memory storage.
The iron( iii ) SCO complex based on the pyruvic acid thiosemicarbazone ligand [Fe(Hthpy)(thpy)]·H 2 O was synthesized and characterized using powder and single-crystal X-ray diffraction, dc magnetic measurements, FT-IR, EPR and Mössbauer spectroscopy.
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Blagov et al. (2024) studied this question.
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