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Interaction of a solution of manganese(III) chloride in acetonitrile with trimethylchlorosilane and trimethylsilyl(tert-butyl)amide produces the green, thermally stable, manganese(VII) compound, MnCl(NBut)3, which has a tetrahedral structure (X-ray).
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Danopoulos et al. (1993) studied this question.
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