A series of fluorinated homopolymers and block co-polymers has been synthesised using the four-coordinate molybdenum ring-opening metathesis polymerisation (ROMP) initiators [Mo(CHR)(NAr)(OR′)2], where R = CMe2Ph, Ar = 2,6-C6H3-Pr2i and R′= CMe3 or CMe(CF3)2.
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Feast et al. (1994) studied this question.
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