The structure of the title compound, Na3Ga5(PO4)4O2(OH)2·2H2O, consists of GaO6 octahedra, GaO5 trigonal bipyramids and PO4 tetrahedra which, by sharing edges and corners, form an open structure containing channels (ca. 4 Å diameter) running along the [001] direction; two water molecules per formula unit can be desorbed.
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Attfield et al. (1995) studied this question.
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