The rate constant of the reaction of ground state S(3P) atoms with molecular oxygen, S(3P) + O2(X3Σg−) → SO(X3Σ−) + O(3P), has been determined as (1.7 ± 0.2) × 1012 cm3 mol−s− at 298 °K by means of kinetic spectroscopy in the vacuum ultraviolet region. The source of S(3P) atoms was the isothermal flash photolysis of COS in the presence of Ar or CO2.
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Fair et al. (1971) studied this question.
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