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December 5, 2025Nature CommunicationsOpen Access

p-nitrobenzyloxycarbonyl protective group as key to automated glycan assembly of neutral human milk oligosaccharides

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Authors

MLMei-Huei LinYKYan‐Ting KuoKHKim Le Mai Hoang

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Overview

Our findings show enhanced chemical synthesis of human milk oligosaccharides by incorporating glucosamine, indicating improved efficiency in oligosaccharide assembly.

Key Points

  • Chemical synthesis efficiency is improved by p-nitrobenzyloxycarbonyl protection of glucosamine.
  • This approach results in enhanced coupling and deprotection for human milk oligosaccharides.
  • Automated glycan assembly techniques allow for the production of diverse HMO structures with excellent purity.
  • Utilizing this method reveals significant potential for versatile applications in oligosaccharide synthesis.

Cite This Study

Lin et al. (2025) studied this question.

synapsesocial.com/papers/694023c82d562116f28fcb04https://doi.org/10.1038/s41467-025-66557-3
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