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A novel coupling method by which a ruthenium(II) complex of a 4′-chloro-substituted 2,2′ : 6′,2″-terpyridine is converted to a dinuclear doubly cyclometallated complex is reported; the dinuclear complex can be oxidized to give a strongly coupled mixed-oxidation state RuIIIRuII species.
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Constable et al. (1993) studied this question.
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