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The segmental bidentate–tridentate ligand L2 reacts with LnIII and ZnII in acetonitrile to give the first self-assembled heterodinuclear d–f triple-helical complexes [LnZn(L2)3]5+(Ln = La, Eu), as determined from solution-phase studies.
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Piguet et al. (1995) studied this question.
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