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Acid hydrolysis of the antibiotic vancomycin from Streptomyces orientalis yields the 3-amino-2,3,6-trideoxy-3-C-methyl-L-lyxo-hexopyranose, vancosamine, the structure of which is assigned on the basis of chemical and spectroscopic studies, particularly n.m.r. spectroscopy.
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Smith et al. (1972) studied this question.
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