Three-co-ordination in lanthanide chemistry: tris[bis(trimethylsilyl)amido]lanthanide(III) compounds

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Abstract

The new compounds M[N(SiMe3)2]3(M = La, Pr, Sm, Eu, Gd, Lu) have been isolated and shown to be the first examples of 3-co-ordinated lanthanides.

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Bradley et al. (1972) studied this question.

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The new compounds M[N(SiMe3)2]3(M = La, Pr, Sm, Eu, Gd, Lu) have been isolated and shown to be the first examples of 3-co-ordinated lanthanides.