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Conditions are described under which an isotope effect on the rate of formation of one reaction product can induce an apparent isotope effect on the label distribution in a second product; reaction of trans-2,3-diphenylmethylene [2-2H1] cyclopropane with Fe2(CO)9 serves to illustrate the utility of the method.
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Samuelson et al. (1981) studied this question.
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