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Trialkylstannyltetrathiafulvalenes undergo palladium-catalysed cross-and homo-coupling reactions to give aryl-substituted tetrathiafulvalenes and bitetrathiafulvalene; the methodology has been applied to the synthesis of p-phenylenebistetrathiafulvalene and 2,5-thiophenediylbistetrathiafulvalene
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Iyoda et al. (1992) studied this question.
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