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Simple acid–base hydrolytic chemistry on the surfaces of glass, quartz or silicon provides an easy access to thin films containing terminal amine and phosphine donor ligands which covalently bind a variety of organometallic complexes, and such oriented ultrathin films supporting a densely packed nickel(0) organometallic complex on glass, catalyse oligomerization of phenylacetylene.
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Petrucci et al. (1995) studied this question.
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