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The structure of a potential strontium MOCVD precursor is studied. Sr(methd)2 [methd = 1‐(2‐methoxyethoxy)‐2,2,6,6‐tetramethyl‐3,5‐heptadionate], an oligoether‐appended strontium complex is shown to be a dimer in solution and liquid state. However, the complex is converted to another dimer during crystallization. A plausible equilibrium mechanism for this reaction is proposed (see Figure).
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Min et al. (2003) studied this question.
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