Bonding interactions between three adjacent hydrogen ligands. Preparation and spectroscopic properties of the tantalum and niobium complexes Ta(H) 3 (C 5 H 5–n R n ) 2 (R = SiMe 3 , n= 1 or 2) and Nb(H 3 )(C 5 H 5–n R n ) 2 (n= 1, R = Me or SiMe 3 ; n= 2, R = SiMe 3 )