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In two binuclear copper(II) complexes of a 30-membered Schiff's base macrocyclic ligand the macrocycle adopts a folded conformation which allows intramolecular linkage of the metal atoms via small bridging ligand (N3– or OH–); the structure of the µ-azido complex has been solved by X-ray analysis.
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Drew et al. (1979) studied this question.
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